2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine

CAS Number 1447947-87-6

Boronates, Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks

2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine MSDS

2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine CAS 1447947-87-6

Covalent Organic Frameworks (COFs) Triazine Ligand

An ethynyl functionalised bridging ligand linker for COFs in application hydrogen evolution reaction and supercapacitors

Overview
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2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine (TBPTRz), CAS number 1447947-87-6, is the pinacol boronate of 2,4,6-triphenyl-1,3,5-triazine. TBPTRz is mainly engaged in the construction of conjugated microporous polymers (CMPs)

Porous aromatic framework material (PAF) LNU-18-800, prepared via a Suzuki coupling reaction of 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine with tris(4-bromophenyl)amine, and then evaluated in an alkali environment (6 M KOH), gave a maximum specific capacitance of 269 F g⁻¹ at a current density of 0.5 A g⁻¹ as electrode material.

Pyrene and 2,4,6-triphenyl-1,3,5-triazine-based conjugated microporous polymers (CMPs), TzSPy and TzPy, synthesized from 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine and dibromopyrenes, exhibited good hydrogen evolution rates of 10.3 mmol g⁻¹ h⁻¹ and 6.93 mmol g⁻¹ h⁻¹, respectively, under simulated sunlight (AM1.5G). Albeit the 1,6-linked TzSPy skeleton possesses a larger torsional angle compared to the 2,7-linked TzPy, it has a higher degree of conjugation to absorb visible light across a broader wavelength range.

MOF and COF ligands

Bpin ligand for cross-linked COF networks

Worldwide shipping

Quick and reliable shipping

High purity

>97% High purity

Facile reactions

Bpin possesses excellent reactivity

General Information

CAS Number	1447947-87-6
Chemical Formula	C₃₉H₉₈B₃N₃O₆
Full Name	2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine
Molecular Weight	687.25 g/mol
Synonyms	TBPTRz, 1,3,5-Triazine, 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-
Classification / Family	Triazines, COF ligands

Chemical Structure

Product Details

Purity	>97%
Melting Point	N/A
Appearance	White powder to fibres/crystals

MSDS Documentation

2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine MSDS Sheet

Literature and Reviews

Pyrene- and 1,3,5-triazine-based D–A two-dimensional polymers for sunlight-driven hydrogen evolution: the influence of the linking pattern, J. Yang et al., Polym. Chem., 13, 5769-5774 (2022); DOI: 10.1039/D2PY00807F.
Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water, C. Meier et al., Polymer, 126, 283-290 (2017); DOI: 10.1016/j.polymer.2017.04.017.
A carbonized porous aromatic framework to achieve customized nitrogen atoms for enhanced supercapacitor performance, Y. Zhao et al., New J. Chem., 43, 18158-18164 (2019); DOI: 10.1039/C9NJ04038B.
A Strategy for the Construction of Triply Interlocked Organometallic Cages by Rational Design of Poly-NHC Precursors, Y. Zhang et al., J. Am. Chem. Soc., 142 (31), 13614–13621 (2020); DOI: 10.1021/jacs.0c06470.
Structurally Diverse Covalent Triazine-Based Framework Materials for Photocatalytic Hydrogen Evolution from Water, C. Meier et al., Chem. Mater., 31 (21), 8830–8838 (2019); DOi: 10.1021/acs.chemmater.9b02825.

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