9,10-Bis(4-formylphenyl)anthracene

CAS Number 324750-99-4

Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks

9,10-Bis(4-formylphenyl)anthracene CAS 324750-99-4

Covalent Organic Frameworks (COFs) Anthracene Ligand

A formyl functional ligand linker for COFs in application of nitrofuran and nitroaromatic explosive detection, photo sterilisation and OLEDs

Overview
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9,10-Bis(4-formylphenyl)anthracene (BFPA), CAS number 324750-99-4, has an anthracene core with two 4-formylphenyl groups at 9,10-positions. Anthracene derivatives are important sources of singlet oxygen (¹O₂).

Porphyrin–anthracene covalent organic framework, Por-DPA-COF, was constructed by using a porphyrin photosensitizer as the active nodes to provide photothermal and photodynamic activities under irradiation, and 9,10-bis(4-formylphenyl)anthracene as the linkage to capture ¹O₂ and release it in the dark. Por-DPA-COF exhibited good photothermal conversion performance and efficient ¹O₂ production capacity thus promoting wound healing without obvious side effects as a novel efficient bactericide.

Luminescent conjugated microporous polymer (AP-CMP), through the polycondensation of 9,10-bis(4-formylphenyl)anthracene with pyrrole, successfully prevented unfavourable quenching due to the aggregation and π-π stacking of highly conjugated anthracene building blocks. The highly extended and conjugated structure enabled AP-CMP with high fluorescence, porosity, and the ability to detect nitrofuran antibiotics selectively and rapidly through fluorescence quenching. AP-CMP had low detection limits of 0.62 ppm for Nitrofurazone (NFZ), 0.67 ppm for nitrofurantoin (NFT), and 0.77 ppm for furazolidone (FZD).

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

Worldwide shipping

Quick and reliable shipping

High purity

>98% High purity

Facile reactions

Aldehyde possesses excellent reactivity

General Information

CAS Number	324750-99-4
Chemical Formula	C₂₈H₁₈O₂
Full Name	9,10-Bis(4-formylphenyl)anthracene
Molecular Weight	386.44 g/mol
Synonyms	BFPA, 4,4'-(Anthracene-9,10-diyl)dibenzaldehyde
Classification / Family	Anthracenes, COF ligands

Chemical Structure

Product Details

Purity	> 98%
Melting Point	295 ºC (lit.)
Appearance	White to off-white powder/crystals

MSDS Documentation

9,10-Bis(4-formylphenyl)anthracene MSDS Sheet

Literature and Reviews

Anthracene and Porphyrin-based Conjugated Microporous Polymer for Nitrofuran Antibiotics and Nitroaromatic Explosives Detection, C. Qi et al., J. Environ. Chem. Eng., 111553 (2023); DOI: 10.1016/j.jece.2023.111553.
Porphyrin–anthracene covalent organic frameworks for sustainable photosterilization, J. Guo et al., J. Mater. Chem. B, 2023, DOI: 10.1039/D3TB02017G.
Anthracene-incorporated cyanostilbene based donor–acceptor systems: intramolecular charge transfer and aggregation induced emission, C. Femina et al., New J. Chem., 47, 13810-13819 (2023); DOI: 10.1039/D3NJ00478C.
Preparation, characterization, pH titration, and electrochemical properties of an anthracene-bridged binuclear ruthenium complex containing imidazole, H. Yin et al., J. Coord. Chem., 72, 2957-2967 (2019); DOI: 10.1080/00958972.2019.1678031.
Functionality-Dependent Electrical Conductivity in Two-Dimensional Covalent Organic Frameworks, S. Bommakanti et al., J. Phys. Chem. C, 127 (17), 8352–8361 (2023); DOI: 10.1021/acs.jpcc.3c01387.
High efficiency in blue organic light-emitting diodes using an anthracene-based emitting material, J. Park et al., Thin Solid Films, 516, 2917-2921 (2008); DOI: 10.1016/j.tsf.2007.06.004.
Exceptional Thermal Stability in a Supramolecular Organic Framework: Porosity and Gas Storage, W. Yang et al., J. Am. Chem. Soc., 132, 41, 14457–14469 (2010); DOI: 10.1021/ja1042935.

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